Orthodontic arch wires: Materials and their properties

Introduction

The optimal force delivery system in orthodontics should be able to deliver the desired force without frequent visits or change, be hygienic and be affordable. A force delivery system should be possible with minimum patient compliance and least operator indulgence.

Orthodontic forces are generated by:

  • 1.

    Wires and their configurations, including springs

  • 2.

    Elastics and rubber bands

  • 3.

    Forces from muscles/functional spaces

  • 4.

    Force from clear aligners

In fixed appliances, wires and their various configurations serve as the primary force delivery system, working in tandem with brackets or similar attachments on the teeth. This force system is a complex interplay of the wire’s alloy composition, physical properties, dimensions, shape and appliance design.

As the idiom goes, ‘an orthodontist is as good as the arch wire he uses’. The orthodontic arch wire is one of the most important active elements of the orthodontic armamentarium and thus requires special consideration.

Definition: What is a wire?

In engineering terms, a wire is a flexible structural or machine component having a working length many times that of its cross-sectional dimension and has the capability of transmitting force along that length.

In orthodontic language, an arch wire refers to a piece of wire secured to two or more teeth, and the dental arch is secured through fixed attachments to cause, guide or control orthodontic tooth movement.

American Dental Association specification no. 32 includes orthodontic wires, excluding precious metals and ligature wires. The desirable properties of the orthodontic wires are summarised in Table 45.1 . Since most wires are made with metals and alloys, several engineering terms are used for the materials. These are summarised in Table 45.2 .

TABLE 45.1

Properties of metal orthodontic wires

  • Aesthetics : The wire should be the least visible in the mouth. This property becomes very important when using ceramic brackets. While this is a very desirable property, there should be no compromise on mechanical properties.

  • Biocompatibility and environmental stability : Biocompatibility refers to resistance to corrosion and tissue tolerance to elements in the wire. The corrosive behaviour is tested according to the international standards ISO 10271. Environmental stability ensures that the desirable properties of the wire are maintained for extended periods of time. This property ensures that the wire is not harmful when in use in the mouth.

  • Biohostability : The ease with which a wire tends to accumulate bacteria, spores or viruses is called biohostability. An ideal arch wire should be a poor host.

  • Coefficient of friction : Friction is resistance to the motion of one material with respect to another closely approximated material. In orthodontics, friction describes the ease of movement of brackets over the wire. If the coefficient of friction is lower, sliding during alignment and space closure will be easier and will have less strain over the anchor segments.

  • Formability : This property describes the ease with which a material may be permanently deformed. Formability allows the wire to bend into desired configurations, such as loops, coils and stops, without fracturing the wire. This property is dependent on the number of slip planes in the crystal lattice of the alloy. The more the slip planes, the easier it is to deform the wire. Formability is measured by employing a 90-degree cold bend test. The wire which can be given the maximum number of bends without fracturing can be termed the most formable. This property is the opposite of springback or flexibility because the most flexible wire can be given the least number of bends.

  • Joinability : This denotes the ability to attach auxiliaries to orthodontic wires by welding or soldering.

  • Range : Range is the distance that the wire bends elastically before permanent deformation occurs. Clinically, this means the distance to which an arch wire can be activated without exceeding the limits of the material. To relate range, stiffness and strength, we can say that the range limits the amount the wire can be bent, and stiffness indicates the force required to reach that limit. The combination of both is the property of strength.

  • Resiliency : Resiliency describes the amount of energy stored in a body when it is elastically deformed. Resiliency is the area under the elastic portion of the stress–strain curve. The resilience of a wire represents the energy absorbing capacity of the material, which is a combination of strength and stiffness. A highly resilient wire will be able to exert force for a larger range and sustain the activation for a longer period. Hence, resilient wires give better control and need fewer wire changes in clinical settings.

  • Solderability : The ease with which attachments can be soldered to the wire.

  • Springback : Springback is a clinically applicable term for maximum elastic deflection, maximum flexibility, the range of activation, the range of deflection or a working range. It is the extent to which a wire recovers its shape after deactivation.

    • Orthodontic wires should have a springback property, which means that the configuration will regain the original shape even after being greatly deformed. This would mean fewer wire changes.

  • Stiffness : It basically refers to the resistance of the wire to deformation. Stiffness also measures the force the wire is capable of delivering for a particular amount of deflection. Low stiffness or load–deflection rate implies that the wire will apply low forces, which will be more constant as the appliance deactivates. Burstone believes that the stiffness of a wire is related to both the material and cross-section. A stiff wire will not be easily deformed and hence used in situations where teeth need to be maintained in their positions. In contrast, wires with less stiffness which produce low forces for large range are required to facilitate tooth movement during active treatment.

  • Strength : A wire’s strength is defined as the force required to activate an arch wire to a specific distance.

    • Stiffness and strength are often confused.

    • Yield strength proportional limit and ultimate tensile strength are various measures of strength (see terminologies for definitions).

  • Toughness : Toughness is defined as the force required for fracturing a material. It can be measured as the total area under the stress–strain graph. Clinically, this property is seen when giving bends in a wire and when giving deflections.

  • Weldability : It is the ease with which the wire can be joined to other metals, by melting the work pieces around the bond. A filler metal may or may not be used in the process. Both the soldering and welding are included in the broad category of joinability. The ability to attach auxiliaries to orthodontic wires by welding or soldering provides an additional advantage when incorporating modifications to the appliance.

  • Zero stress relaxation : If a wire is deformed and held in a fixed position, the stress in the wire diminishes with time, but the strain remains constant. This is known as stress relaxation. At the molecular level, this occurs due to slippage of particles over each other when subjected to forces leading to loss of activation in the wire. Zero stress relaxation is the property of a wire to give constant light force when subjected to external forces. This property is desirable if a wire is to provide constant forces for a longer period of time, especially in springs and loops.

TABLE 45.2

Some common terms and their definitions related to metals used in orthodontics

  • Annealing : It is the process of reversing the effects of cold working, such as strain hardening, distorted grains, etc. by simply heating the metal. In a clinical setting, a wire is considered annealed when it appears red hot.

  • Bauschinger effect : The phenomenon is named after German engineer Johann Bauschinger in 1886. Essentially, the Bauschinger effect describes the reduction in yield stress of a metal when the direction of deformation is reversed. If you permanently deform a metal in one direction, its yield stress is reduced in the opposite direction. The effect does not apply in the direction the metal has been strained. This can be used to advantage after wire bending because of residual stresses left in the material, improving its elastic properties in the direction in which the wire has been deformed.

  • Brittleness : This is considered the opposite of toughness. A brittle material cannot undergo plastic deformation.

  • Crack propagation : Crack propagation is seen especially in high tensile wires which have a high density of dislocations and lattice imperfections. The dislocations pile up and form a minute crack. The stress concentration at this point is very high, so that only small stress can result in crack propagation. The crack continues to propagate, and it appears at the surface some distance from the point where it is bent. This fracture appears as if the skin of the wire has been peeled off from the main wire.

  • Cyclic fatigue : If there is repeated cyclic stress of a magnitude below the fracture point of a wire, then fracture of the wire can occur. This is due to cyclic fatigue.

  • Elastic limit : It describes the greatest load to which the wire can be subjected, such that it returns to its original form. If 0.1% deformation is allowed, then it is quantified as the elastic limit. After this point, when the load on the wire is removed, it does not return to its original length.

  • Flexibility : When a material can undergo a large deformation (or large strain) with minimal force, within its elastic limit, it can be termed as flexible.

    • Maximal flexibility is the strain that occurs when a wire is stressed to its elastic limit.

    • Max flexibility = Proportional limit Modulus of elasticity

  • Heat treatment refers to a general process of using thermal energy to change the characteristics of metallic alloys, such as tempering, precipitation hardening or annealing. In a clinical setting, different wires are heat treated according to the manufacturer’s recommendations. A wire is considered heat treated when it appears straw coloured.

  • Hysteresis : The difference between the energy required to activate the wire by deflection and that released by it during deactivation is called energy loss or hysteresis.

  • Modulus of elasticity : According to Hooke’s law, the stress and strain are directly proportional to each other in the elastic portion of the graph. The ratio of the stress in the spring and applied force (but only within its proportional limit) is called the modulus of elasticity and is a constant for a given material.

  • Proportional limit : It is the point on the graph at which a permanent deformation is first observed. Although the definitions differ, the elastic limit and proportional limit, for all practical purposes, represent the same point.

  • Sensitisation : When stainless steels are heated up to temperatures between 800°F and 1200°F, carbon reacts with chromium to form chromium carbide; hence, chromium tied up, as the carbide cannot contribute to the corrosion resistance of the metal. This phenomenon is called sensitisation. The carbon inactivates the chromium at the grain boundaries opening them to corrosion.

  • Stabilisation : This is the process by which carbon is made unavailable for sensitisation. Steel that has been treated to reduce the available carbon is called stabilised steel.

  • Strain : It is the internal distortion produced by the load. It is defined as deflection per unit length.

    • Strain = Change in length Original length

  • Strain, work hardening or cold working is the process of plastically deforming metal at a temperature lower than that at which it recrystallises new grains. This temperature is usually one-third to one-half of its absolute melting point. Cold working disrupts the normal atomic arrangement and incorporates strain across the grain boundaries.

  • Stress : It is the internal distribution of a load applied to a material. It is usually defined as force per unit area (F/A).

    • Stress = Internal force Area of action

    • Tensile stress is caused by a load that tends to stretch the body.

    • Compressive stress is caused by a load that tends to compress the body.

    • Shear stress is caused by a load that tends to slide one part of a body over another.

  • Ultimate tensile strength : The maximum force that a wire can withstand before it fractures is denoted as the ultimate tensile strength. This is always higher than the yield strength, and clinically, it is usually the indicator of the maximum force that the wire can deliver.

  • Yield strength : This denotes the amount of stress on the stress–strain graph that causes a certain amount of permanent deformation (usually 0.1%) is calculated. This is called the yield strength.

Wire dimensions

The wire dimension expressed in terms of thousands of an inch/mm, mil or gauge. Dimensions of wire are judged by its cross-sectional dimensions. The most popular international standards for adhering to this specification are mentioned in International Organisation for Standardisation (ISO/CD) 15841.

The ISO 15841:2014 standard, last reviewed in 2020, specifies requirements and test methods for preformed orthodontic arch wires, excluding springs or other preformed components.

The Deutsches Institut für Normung e.V. (DIN) standard, published in January 1998 by the German Institute for Standardization, specifies measurement tolerances for orthodontic wires (NA 014-00-19 AA). This standard is more stringent than the tolerance zones in ISO 15841:2014/Amd 1:2020.

  • Round wires are available in the dimensions of 0.010, 0.012, 0.014, 0.016, 0.018, 0.020 and 0.022 in. ( Tables 45.3 and 45.4 ).

    TABLE 45.3

    Wires cross-section/types and material ( Fig. 45.1 )

    Wire cross-section Wire strands Wire material
    Round Single-stranded Metals and alloys
    Square Multistranded Shape-memory polymers (SMPs)
    Rectangular Twisted or braided Polymers (composite)
    Combination of round and rectangular Co-axial Metals with synthetic coatings

    TABLE 45.4

    Round wires

    Advantages Disadvantages
    • Larger deflection; hence, can be engaged in teeth with discrepancy of alignment

    • Easy to bend and create shapes and loops

    • Increased play allows tipping movement

    • Reduced friction

    • Rolling of wire in the bracket slot

    • It cannot effectively cause torque

  • Square wires are available in the dimensions of 0.016 × 0.016 in.

  • Rectangular wires are available in the dimensions of 0.016 × 0.022, 0.017 × 0.025, 0.018 × 0.025, 0.019 × 0.025 and 0.0215 × 0.0275 in. A rectangular wire, therefore, has a thickness and width which corresponds to the bracket slot. The standard size of bracket slots is 0.022 × 0.028 or 0.018 × 0.025 in. ( Table 45.5 ).

    TABLE 45.5

    Rectangular and square wires

    Advantages Disadvantages
    • It can allow bodily tooth movement

    • Precise 3D control

    • Better orientation to bracket

    • Better control of tooth movement

    • Can initiate and produce effective torque

    • Difficult to bend and give shape, rarely free of torque

    • High friction

    • Difficult to engage in clinical situations where teeth are positioned in discrepancy

The thickness (height) of a rectangular wire is usually the smaller dimension, and it fills the height of the slot of the bracket. It is the dimension in the plane of the bend. The width of a rectangular wire is usually the larger dimension, and it fills the depth of the slot of the bracket. Hence, in edgewise mode, a 0.017 × 0.025 in. rectangular wire has a thickness of 0.017 in. and a width of 0.025 in. ( Fig. 45.1 ).

Figure 45.1

Wires in cross-sections:

  • i.

    Round wire

  • ii.

    Square wire

  • iii.

    Rectangular wire: (iiia) rectangular wire in edgewise bracket and (iiib) rectangular wire in ribbon mode.

  • iv.

    Triangular wire

  • v.

    Braided round wire (3 strands)

  • vi.

    Braided wire (8 strands)

  • vii.

    Coaxial round wire

A rectangular wire can be bent in ribbon mode (flat wire), with a thickness greater than the width ( Fig. 45.1iiib ).

Modes of rectangular wire are as follows ( Fig. 45.2 ):

  • Edgewise/conventional mode

  • Ribbon arch mode

Figure 45.2

Bi-dimensional wires.

(A) Anterior segment (B) Posterior segment.

Triangular wires

In 2001, Broussard and Graham introduced the use of a stainless steel (SS) wire with a triangular cross-section. The equilateral triangle has a mean dimension of 0.030 in. and rounded-off edges in cross-section. Compared to round or rectangular wires, triangular wires offer superior adaptation in interproximal areas, better patient comfort, improved periodontal health and excellent appliance stability. Triangular wires are used in various clinical applications, including bonded and removable retainers ( Fig. 45.1iv ).

Dual geometry wires

The SPEED (298, Shepherd Avenue Cambridge Ontario, N3C 1V1, Canada) self-ligating appliance system uses a dual geometry arch wire that is optimised for efficient sliding mechanics in the posterior region due to its round cross-section and effective torque control in the anterior segments, thanks to the square segment. The arch wire is made of SS and has a high tensile strength ( Fig. 45.2 ).

The 0.018 in. slot bracket uses a dual geometry wire to achieve precise torque control in the anterior segment, with a square 0.018 × 0.018 in. arch wire. The buccal segments, on the other hand, employ round 0.018 in. arch wire for efficient sliding mechanics. For use in 0.022 in. bracket slot size, the anterior segment of the arch wire has square 0.021 × 0.021 in. dimensions and the buccal segments have a round wire of 0.020 in.

Properties of ideal arch wire are tabulated in Table 45.6 .

TABLE 45.6

Properties of ideal arch wire

  • High springback capacity

  • Flexibility and resiliency

  • Large working range

  • Excellent biocompatibility

  • Poor biocompatibility

  • Smooth surface-less coefficient of friction (dry and wet state)

  • Able to deliver continuous light forces

  • Cost-effective/affordable

Evolution of orthodontic wires

The orthodontic arch wires have evolved over time, mainly with the development of metallurgy and the science of alloys and the testing of their properties inside and outside the mouth.

Early era: The correction of dental irregularities dates back to 400 BC by Hippocrates with some kind of tying. Catgut and silk thread were also used. But gold ligatures are the first ever reported wires in orthodontics. Noble metals such as gold, platinum and silver were used to manufacture wires because of their ductility, formability, biological safety and inertness in the oral environment.

Wires in the 1880s: The precursor of the orthodontic wire used in treatment in the late 1800s was the ‘arch bow’. The typical arch bow was a round, threaded stiff wire drawn from a nickel–silver or platinum–gold alloy to a diameter of 0.032–0.036 in. attached to the bands using nuts. Angle’s ribbon arch appliance utilised a gold–platinum alloy combination as the arch wire.

Dr. Edward H. Angle (1887) introduced ‘Neusilber’ or nickel–silver alloys, also called German silver, in the United States. These were alloys of Cu 47–65%, Ni 10–25% and Zn 15–42% that did not contain any silver. He was able to obtain favourable clinical properties by cold working to various degrees. But this was strongly opposed as they tend to discolour in the mouth.

1900s: The SS alloys were used for orthodontic appliance fabrication in 1919. The wires of noble metal were replaced by SS wires, which were much less expensive and yet exhibited the desired properties of corrosion resistance in the oral environment, excellent strength and desired springback on activation. These indeed replaced noble metals primarily because of their desirable properties such as corrosion resistance, excellent strength and low-cost, springback.

In 1950, the Elgin Watch Company (United States) developed Elgiloy (Co–Cr–Ni), which has useful properties of excellent formability and exhibits the necessary strength after heat treatment. The alloy was adapted for use in orthodontic arch wires. These wires were corrosion resistant and inexpensive.

In 1963, William Buehler developed the nickel–titanium alloy. It was introduced into dentistry by George Andreasen because of its property of shape memory effect (SME). This alloy could regain its original preset shape when heated. These wires are much more advanced now and remain the mainstay wires in the initial alignment stages.

Burstone and Goldberg (1980) introduced wires made of a new alloy called ‘Titanium–molybdenum alloy’ (TMA). TMA wires have been found to have significant uses in clinical orthodontics because these alloy wires have useful mechanical properties for enhanced performance compared to steel.

Twenty-first century: To improve the aesthetics of orthodontic appliances, tooth-coloured wires like Optiflex wires and Teflon-coated wires have been introduced. These wires, which have a non-metallic appearance, are indicated in combination with aesthetic ceramic or plastic brackets ( Tables 45.7–45.9 ).

TABLE 45.9

The shape of wire (round, square or rectangular) vis-à-vis wire properties

Round wire in bending Round wire in torsion Rectangular wire in bending Helical spring in axial tension or compression
Stiffness • r 4 /l 3 Stiffness • r 4 /l Stiffness • (thickness) 3 width/l 3 Stiffness • 1 ( coil diameter ) 3 ( no . of coils ) Not dependent on cross-section
Strength • r 3 /l Strength • r 3 .
Not dependent on the length
Strength • (thickness) 2 width/l Strength • 1 coil diameter Not dependent on cross-section and no. of coils
Range • l 2 /r 3 Range • l/r Range • l 2 /thickness.
Not dependent on width
Range • (coil diameter) 2 × (no. of coils).
Not dependent on cross-section

r, diameter; l, length.

TABLE 45.7

Metal composition and properties of orthodontic wires

Wire composition Stiffness Springback Load–deflection rate Biocompatibility Resiliency Joinability Friction Formability Cost
  • 1.

    Stainless steel

High Low Highest Good Low Good but the welded joint needs to be soldered Very low Good Lowest
  • 2.

    Elgiloy (Rocky Mountain Orthodontics)

High Low Comparable to SS Good Low Good, but welded joint needs to be soldered Low to moderate Very good Low
  • 3.

    M-NiTi

Low High 1/4 of SS Some corrosion noted High Not solderable or weldable Higher than SS Poor Moderate
  • 4.

    β-Ti

Average Average 1/2 of SS Very good Good but lower than NiTi Truly weldable and solderable Very high Good High
  • 5.

    A-NiTi (Chinese and Japanese NiTi)

Low Four times of SS and higher than M-NiTi Lower than M-NiTi Better than M-NiTi Better than M-NiTi Not solderable or weldable Higher than SS Poor Very high
  • 6.

    Cu-NiTi

Lowest Higher than all Lowest Better than M-NiTi Better than M-NiTi Not solderable or weldable Higher than SS Poor Very high
  • 7.

    Multistrand SS

Low High Comparable to A-NiTi Good High Good but the welded joint needs to be soldered Very low Poor Low

A-NiTi, austenitic/nickel–titanium; B-Ti, beta-titanium; Cu-NiTi, copper/nickel–titanium; M-NiTi, martensitic nickel–titanium.

The field of wire technology has advanced with the introduction of shape-memory polymers (SMPs) . These polymers are a type of ‘actively moving’ materials that can change from one shape to another. They can be temporarily shaped through mechanical deformation and then fixed to obtain a new shape. This unique property of SMPs opens up many possibilities for their application in orthodontics.

Stainless steel wires

By the late 1930s, thorough research and efficacy in clinical applications established SS as the mainstay orthodontic wire material, replacing noble metals. Steels are iron-based alloys that usually contain less than 1.2% carbon. SS contains a minimum of 10%–13% chromium and 8% nickel, which gives it ‘rust-free properties’ and so the name. SS consists of mainly three types:

  • Ferritic SS (400 series)

  • Austenitic SS (300 series)

  • Martensitic SS (400 series)

Austenitic stainless steels (300 series)

Austenitic steels are used for orthodontic wires and bands. This family of alloys was named after the British metallurgist Roberts Austen. All American Iron and Steel Institute (AISI) numbers in the series of 300 are austenitic. Due to the presence of a significant amount of nickel and chromium, these alloys are the most corrosion resistant of all the SS.

AISI 302 is the primary type of steel containing 18% chromium, 8% nickel and 0.15% carbon.

AISI 304 has a similar composition, but its carbon content is 0.08%. Both 302 and 304 may be designated as 18–8 SS.

Low carbon AISI Type 316L and nickel-free ASTM Type F2229 wires are also available.

Round orthodontic wires are manufactured by a proprietary drawing sequence that involves several stages with intermediate annealing heat treatments.

Rectangular orthodontic wires are manufactured from round wires by a drawing process utilising a Turk’s head apparatus. Therefore, the edges of the rectangular wires may be somewhat rounded which limits their torque expression.

Properties of SS wires , are briefly tabulated in Table 45.10 .

TABLE 45.10

Properties of stainless steel (SS) wires ,

  • Formability:

    • SS wires have excellent formability and can be bent into various designs without fracture within limits. These wires have the lowest coefficient of friction and are ideal for use during retraction mechanics.

  • Stiffness:

    • SS is a relatively stiff material with low flexibility and a small range of action. Hence, it cannot withstand large activations or recover shape entirely from the initial deformation. A steep load–deflection rate means that forces delivered by the SS wires dissipate rapidly over a very short amount of deactivation.

  • Soldering:

    • SS wires have ease of joining as they can be easily welded or soldered. Usually, the welded areas need a solder reinforcement.

  • Biocompatibility:

    • In general, the SS wires have excellent biocompatibility and high corrosion resistance in the oral environment.

  • Low cost:

    • The cost factor is also favourable for SS wires because they are quite inexpensive.

  • Sensitivity:

    • Hypersensitivity reactions due to the leaching of Ni and Cr have been reported, but these are restricted to a minuscule percentage of the population.

High tensile australian wires

A.J. Wilcock (AJW) Sr., an engineer and entrepreneur, in collaboration with Dr. P.R. Begg, an orthodontist in Adelaide, developed pre-heat-treated cold-drawn steel wires that were more resilient than SS and had higher tensile strength.

These wires (AJW) were designed exclusively for use with Begg’s light wire technique. They are graded according to the increasing order of resiliency and yield strength. The resilient wires are highly brittle and break easily, and they are relatively more expensive than SS wires. As these wires developed in Australia were to be used with Begg’s technique, they are popularly called Australian wires, Begg wires or AJ Wilcock wires.

AJW wires are available according to the straightening processes ( Table 45.8 , Figs 45.3 and 45.4 ), spinner or pulse.

  • Spinner straightening is a mechanical process of straightening resistant materials, usually in cold-drawn conditions. The wire is pulled through rotating bronze rollers, which twist it into a straight shape. This process has disadvantages, including permanent deformation and a decrease in yield strength value as the wires are strain softened.

  • Pulse straightening is a recent and more accepted method of wire straightening. Here, the wire is pulled in a special machine, which permits lower diameters of high-tensile wires to be straightened. The surface has a smoother finish and, therefore, lower friction. Pulse-straightened wires are better in properties regarding ultimate tensile strength, high load–deflection rate, significantly higher working range and lower frictional resistance.

TABLE 45.8

Grades and wire dimensions of AJ Wilcock Australian wires

A. AUSTRALIAN (AJW) ORTHODONTIC WIRES ARE AVAILABLE IN DIFFERENT GRADES AND DIAMETERS
Wire grade Size (diameter), inches
Regular 0.012–0.024
Regular + 0.012–0.020
Special 0.012–0.020
Special + 0.012–0.024
Premium 0.012–0.020
Premium + 0.010–0.018
Supreme 0.008–0.011
B. AUSTRALIAN (AJW) PULSE-STRAIGHTENED WIRES
Grade Diameter in inches
Special + 0.014, 0.016, 0.018
Premium 0.020
Premium + 0.010, 0.011, 0.012, 0.014, 0.016, 0.018
Supreme 0.008, 0.009, 0.010, 0.011, 0.012
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May 10, 2026 | Posted by in Orthodontics | 0 comments

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